Sorption-desorption kinetics and toxic cell concentration in marine phytoplankton microalgae exposed to Linear Alkylbenzene Sulfonate     

Renaud F  Oberhänsli F  Teyssié JL  Miramand P  Temara A  Warnau M 《Marine pollution bulletin》2011,62(5):942-947

Linear Alkylbenzene Sulfonates (LAS) are ubiquitous surfactants. Traces can be found in coastal environments. Sorption and toxicity of C₁₂-LAS congeners were studied in controlled conditions (2-3500 μg C₁₂LAS/L) in five marine phytoplanktonic species, using standardized methods. IC₅₀ values ranged from 0.5 to 2 mg LAS/L. Sorption of ¹⁴C₁₂-6 LAS isomer was measured at environmentally relevant trace levels (4 μg/L) using liquid scintillation counting. Steady-state sorption on algae was reached within 5 h in the order dinoflagellate > diatoms > green algae. The sorption data, fitted a L-type Freundlich isotherm, indicating saturation. Desorption was rapid but a low LAS fraction was still sorbed after 24 h. Toxic cell concentration was 0.38 ± 0.09 mg/g for the studied species. LAS toxicity results from sorption on biological membranes leading to non-specific disturbance of algal growth. Results indicate that LAS concentrations in coastal environments do not represent a risk for these organisms.  相似文献   

三峡水库初期蓄水对长江口淡水资源的影响   总被引：13，自引：2，他引：13       下载免费PDF全文

曹勇  陈吉余  张二凤  陈沈良  曹卫承 《水科学进展》2006,17(4):554-558

2003年6月1~15日和同年10月20~31日三峡水库进行了初期蓄水。6月份水库蓄水后使下游大通流量减少了37%,长江口的淡水资源的持续时数降低了40%,最大盐度增加了3倍,平均盐度增加了6倍;10月份水库蓄水使大通流量减少了1/2,淡水资源的持续时间呈现下降趋势,最大盐度增加了3倍左右,平均盐度也有类似的表现。再从流量的沿程变化、流量的变化程度、影响河口淡水的持续时间、河口淡水资源影响因子方面进行了讨论,认为三峡蓄水是这两次河口淡水资源减少的主要原因。  相似文献   

多孔介质中水敏性应用的研究综述     

张晓辉  郑西来  林国庆  吴俊文  周骏 《水文地质工程地质》2006,33(4):81-84

水敏现象在石油、岩土和环境工程等领域广泛存在。有效地控制水敏现象的发生，不仅具有科学意义，还有一定的经济价值。本文在广泛查阅国内外研究成果的基础上，总结了水敏性在石油、岩土和环境工程方面应用的研究进展，并在此基础上提出了水敏性研究的发展方向。  相似文献   

The acid neutralizing capacity （ANC） of South Africa＇s freshwater ecosystems     

Stephanie de Villiers 《中国地球化学学报》2006,25(B08):146-146

Acidification is considered the most important one of the primary chemical stress factors that impact on freshwater ecosystems. In unpolluted freshwater systems, the primary controls on the degree of acidification are factors such as the geological substrate of the catchment area, the presence of organic acids secreted by vegetation in the river system, and equilibrium exchange of carbon dioxide with the atmosphere. Anthropogenic factors that can impact on the degree of acidification of freshwater systems include agricultural, mining and industrial activities, either through direct runoff into river systems or through deposition of atmospheric pollutants from these sources. The capacity factors alkalinity and acidity, which represent the acid- and base-neutralizing capacity （ANC and BCN） of an aqueous system, have been used as more reliable measures of the acidic character of freshwater systems than pH. Unlike pH, ANC and BNC are not affected by parameters such as temperature and pressure. Therefore, ANC has been employed as a predictor of biological status in critical load assessments. Freshwater systems with ANC＇s eq/L isμeq/L are considered sensitive to acidification, ANC=0 μbelow 150 commonly used as the predictor for fish species such as trout in lakes, and an eq/L as more realistic for streams. Acid-neutralizing capacity μANC value of 40 （ANC） can be determined by titration with a strong acid to a preselected equivalence point. Alternatively, it can be calculated as the difference between base cations （[BC]） and strong acid anions （[SAA]）： ANC=[BC]- [SAA]=[Ca^2＋]＋[Mg^2＋]＋[Na^＋]＋[K^＋]-[SO4^2-]-[NO3^-]-[Cl^-] To date, there has been no attempt to establish the ANC of South Africa＇s freshwater ecosystems or variability therein, despite the fact that long-term water quality monitoring data exist for all the parameters needed to calculate it according to the above equations. As a result, the relationship between the acid neutralizing capacity of freshwater ecosystems in South Africa and biodiversity factors, such as fish status, is unknown. Results of the first comprehensive （country-wide scale） evaluation of the acid neutralizing capacity of river systems in South Africa will be presented. Long-term monitoring data obtained from the Department of Water Affairs and Forestry （DWAF） from most of South Africa＇s river systems were used to establish geographic and temporal variabilities in ANC. The results show that the Berg and Breede River systems are most susceptible to acidification, and that geological substrate appears to explain most of the geographic variabilities observed.  相似文献   

优质淡水珍珠的体色及其与拉曼光谱的关系   总被引：2，自引：0，他引：2  

秦作路  马红艳  木士春  童张法 《矿物学报》2007,27(1):73-76

对不同颜色的优质淡水养殖珍珠进行激光拉曼光谱的研究,并试图从中找出珍珠颜色与其中的有机物以及和拉曼光谱的关系。结果发现,和纯白色系列优质珠相比,粉红色系列优质珠多了1134和1526 cm-1两个峰;紫色系列优质珠中的1017,1295,2231,2609 cm-1在纯白色珍珠和粉红色系列中均未曾出现;在有色珍珠中探测到某有机物的拉曼峰:由C—C伸缩振动引起的1121,1134 cm-1及C=C伸缩振动引起的1503,1526 cm-1,推测此有机物为聚乙炔类物质,不同于以前的研究者所认为的类胡萝卜素。不同色系的珍珠,其拉曼光谱有着明显的区别;随着同色系颜色的加深,有机物拉曼谱峰的强度也越来越强。  相似文献   

甜水海微陆块上二叠系地层的厘定及其特征     

边小卫  王炬川  罗乾周  杨克俭  朱海平  杨运军 《陕西地质》2005,23(2):44-49,75

笔者在《岔路口》等四幅1：25万区域地质调查工作中，在红山湖一带从前人所划的石炭系地层中解体出一套二叠系地层，并对其进行了详细的岩石地层、生物地层和层序地层研究，拟新命名为红山湖组，时代为中二叠世。该地层为甜水海微陆块上稳定型的碳酸盐岩建造，与陆块南北两侧二叠系特征截然不同。该套地层的发现填补了微陆块上二叠系地层的空白，对古特提斯多岛洋研究具有重要意义。  相似文献   

松辽盆地白垩纪地层特征   总被引：6，自引：0，他引：6  

尹殿奎 《吉林地质》2004,23(3):1-5,35

松辽盆地发育一套比较完整的白垩纪地层组合，主要为湖相细碎屑岩和泥质岩夹有机岩。是主要的生油岩系。从上到下共划分为7个旋回，含有多门类的淡水化石。盆地中蕴藏丰富的油气、油页岩、二氧化碳等矿产资源。  相似文献   

COMPARATIVE STUDIES OF INORGANIC CARBON UTILIZATION IN EMILIANIA HUXLEYI AND SOME NON-CALCIFYING MARINE MICROALGAE     

董良峰  Merrett M.J.  吴超元 《中国海洋湖沼学报》1999,(3)

INTRODUCTIONMarinemicroalgaeacquiretheirinorganiccarbonforphotosynthesisfromseawaterwhereinorganiccarbonmaybepresentasfreeCO2 ,H2 CO3andHCO-3 andCO2 -3 .TheproportionsofdifferentDICformsareprimarilyrelatedtopH ,andtotemperatureandsalinitytoalessextent.ThetotalDICisashighas2mmol Linseawa terbutthisismainlyintheformofHCO-3 .InnormalpHrangeof7.8-8.2inseawater,HCO-3 accountsfororethan 90 %ofthetotalDIC,whilefreeCO2 islessthan1 % .TheequilibriumconcentrationoffreeCO2 isonly1 2 μm…  相似文献   

中国濒危淡水鱼类致危成因分析   总被引：4，自引：0，他引：4  

乐佩琦 《湖泊科学》1995,7(3):271-276

中国１０００多种淡水鱼类因受水工建设、围湖造田、乱伐滥垦等改变和破坏水域环境、酷渔滥捕，水体污染，不合理引种，法制不全及执法不力等原因导致部分鱼类濒危。初步确定为９２种，分属９目，２４科，７８属，根据程度分为四个等级，绝灭４种，稀土２３种，濒危２８种，渐危３７种。  相似文献   

利用贝类(Lamprotula)化石碳氧同位素再建山西丁村地区晚更新世气候环境   总被引：3，自引：0，他引：3  

李玉成  黄宝玉  徐永昌 《沉积学报》2001,19(4):648-651

较大的湖泊中的贝类生长线的氧同位素可能记录了季节性的温度变化。对拔氏丽蚌 (楔丽蚌 )Lamprotula(Cuneolamprotula)bazini (Heude)和环带丽蚌 (丽蚌 )Lamprotula (Lamprotula)zonata (Heude)的生长线进行氧同位素研究表明,前者有较强的适应环境变化的能力。δ18O值记录的襄汾地区晚更新世的古温度为 2 0～ 2 4℃至 30～34℃,古降雨量多出现代 2 0 0～ 2 6 7mm,河水排泄不畅,积水成湖。这些结果给人的启示是:全球变暖后,该地区气温可能有较大升幅 ;降雨量的增加有可能在排水不畅地区形成水灾,应注意防患于未然。  相似文献